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Bloch-Siegert shift : ウィキペディア英語版 | Bloch-Siegert shift
The Bloch-Siegert shift is a phenomenon in quantum physics that becomes important for driven two-level systems when the driving gets strong (e.g. atoms driven by a strong laser drive or nuclear spins in NMR, driven by a strong oscillating magnetic field). When the rotating wave approximation (RWA) is invoked, the resonance between the driving field and a pseudospin occurs when the field frequency is identical to the spin's transition frequency . The RWA is, however, an approximation. In 1940 Bloch and Siegert showed that the dropped parts oscillating rapidly can give rise to a shift in the true resonance frequency of the dipoles. ==Rotating wave approximation== In RWA, when the perturbation to the two level system is , a linearly polarized field is considered as a superposition of two circularly polarized fields of the same amplitude rotating in opposite directions with frequencies . Then, in the rotating frame(), we can neglect the counter-rotating field and the Rabi frequency is :
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